Percent Concentration
Calculation steps
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General Chemistry • Solutions and Their Physical Properties
Percent concentration expresses the ratio of solute to the entire solution multiplied by 100. Common forms are mass percent (w/w), volume percent (v/v), mass/volume percent (w/v), and mole percent.
Mass percent uses % = (m_solute / m_solution) x 100 and volume percent uses % = (V_solute / V_solution) x 100. The solution amount is the total (solute + solvent) for the chosen basis.
Mass/volume percent is defined as % (w/v) = (m_solute in g / V_solution in mL) x 100. It is often interpreted as grams of solute per 100 mL of final solution volume.
Mole percent is % = n_solute / (n_solute + n_solvent) x 100. If you start from mass, convert using n = m/M, where M is the molar mass determined from the chemical formula.
In percent calculations, the ratio must compare the same type of quantity (grams with grams, mL with mL, or moles with moles). Mixing units breaks the ratio and leads to incorrect percent concentration.