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NaOH Molar Mass (Sodium Hydroxide) — Step-by-Step Calculation

What is the NaOH molar mass, and how is it calculated from periodic-table atomic masses?

Subject: General Chemistry Chapter: Chemical Compounds Topic: Molecular Mass and Formula Mass Answer included
naoh molar mass sodium hydroxide molar mass NaOH molecular weight formula mass molar mass calculation atomic mass periodic table grams per mole
Accepted answer Answer included

NaOH molar mass (sodium hydroxide)

The naoh molar mass is the mass of one mole of sodium hydroxide, determined from the compound’s chemical formula and periodic-table atomic masses.

Key idea: For a compound, molar mass equals the sum of each element’s atomic mass multiplied by its subscript in the formula.

Step 1: Read the formula and count atoms

Sodium hydroxide has formula NaOH. The subscripts are implicit:

  • Na: 1 atom
  • O: 1 atom
  • H: 1 atom

Step 2: Look up atomic masses (periodic table)

Typical periodic-table values (rounded reasonably) are: Na ≈ 22.99, O ≈ 16.00, H ≈ 1.008 (in g/mol per atom in the formula).

Element Atoms in NaOH Atomic mass (g/mol) Contribution (g/mol)
Na 1 22.99 \(1 \times 22.99 = 22.99\)
O 1 16.00 \(1 \times 16.00 = 16.00\)
H 1 1.008 \(1 \times 1.008 = 1.008\)

Step 3: Add contributions to get the NaOH molar mass

\[ M(\mathrm{NaOH}) = (1)\,M(\mathrm{Na}) + (1)\,M(\mathrm{O}) + (1)\,M(\mathrm{H}) \]

\[ M(\mathrm{NaOH}) = 22.99 + 16.00 + 1.008 = 39.998 \ \text{g/mol} \approx 40.00 \ \text{g/mol} \]

Therefore, the NaOH molar mass ≈ 40.00 g/mol. The same numerical value is often called the formula mass (or molecular weight) depending on context.

Na ≈ 22.99 O ≈ 16.00 H ≈ 1.008 0 20 40 g/mol Contribution to \(M(\mathrm{NaOH})\) (approximate)
The stacked bar partitions the NaOH molar mass into element-by-element contributions (Na, O, H) based on their atomic masses.

Common checks and a quick application

  • Unit check: atomic masses add to give g/mol, the standard unit for molar mass.
  • Reasonableness: sodium (≈23) plus oxygen (≈16) already totals ≈39, so the final value should be near 40.
  • Using molar mass: converting between moles and grams uses \(m = n \times M\). For example, \[ m = (2.50\ \text{mol}) \times (40.00\ \text{g/mol}) = 100.0\ \text{g}. \]
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