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Fe2O3 Compound Name (Iron(III) Oxide)

What is the compound name for Fe2O3, and how is it determined from charges and oxidation states?

Subject: General Chemistry Chapter: Chemical Compounds Topic: Naming Binary Compounds of Metals and Nonmetals Answer included
fe2o3 compound name iron(III) oxide ferric oxide Fe2O3 name naming ionic compounds binary ionic compound oxidation state Roman numeral naming
Accepted answer Answer included

Fe2O3 compound name

Result: Fe2O3 is iron(III) oxide (also called ferric oxide).

Why the name is iron(III) oxide

Fe2O3 is a binary ionic compound: iron (Fe) is a metal that forms cations, and oxygen (O) is a nonmetal that forms oxide anions. Oxygen almost always has charge 2− in simple ionic compounds (oxide, O2−).

Step 1: Assign the anion charge

Oxygen in oxides is O2−. With three oxygens, the total negative charge is: \[ 3 \cdot (-2) = -6 \]

Step 2: Determine the iron oxidation state

A neutral formula unit has total charge \(0\). Let iron’s oxidation state be \(x\). With two Fe atoms: \[ 2 \cdot x + 3 \cdot (-2) = 0 \] \[ 2x - 6 = 0 \quad \Rightarrow \quad 2x = 6 \quad \Rightarrow \quad x = +3 \]

Step 3: Apply ionic naming rules

For transition metals that can form more than one cation, the metal’s charge is written as a Roman numeral in parentheses:

Part Species Charge / oxidation state Name used in compound
Cation Fe \(+3\) iron(III)
Anion O \(-2\) oxide
Combined Fe2O3 Total charge \(0\) iron(III) oxide

Visualization: charge balance that leads to Fe2O3

Cations Fe 3+ Fe 3+ Total: +6 + Anions O 2− O 2− O 2− Total: −6 Fe2O3 (net 0)
Two Fe3+ ions contribute a total charge of \(+6\), and three O2− ions contribute a total charge of \(-6\); the smallest whole-number ratio that balances to zero is Fe2O3, which is named iron(III) oxide.

Common mistake to avoid

The Roman numeral in iron(III) oxide refers to iron’s oxidation state (\(+3\)), not the subscript “2” in Fe2O3. Subscripts come from charge balance; Roman numerals come from the cation’s charge.

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