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CuSO4: Copper(II) Sulfate Name, Ions, Charges, and Molar Mass

In general chemistry, what is CuSO4, what is its correct name, and how are its ions, charges, and molar mass determined?

Subject: General Chemistry Chapter: Chemical Compounds Topic: Naming Salts with Polyatomic Ions Answer included
cuso4 CuSO4 copper(II) sulfate copper sulfate formula sulfate ion SO4 2- polyatomic ions oxidation state copper
Accepted answer Answer included

The formula cuso4 corresponds to \(\mathrm{CuSO_4}\), a common ionic compound in general chemistry that contains the polyatomic sulfate ion.

Key identification: \(\mathrm{CuSO_4}\) is copper(II) sulfate, composed of \(\mathrm{Cu^{2+}}\) and \(\mathrm{SO_4^{2-}}\).

Step 1: Interpret the chemical formula \(\mathrm{CuSO_4}\)

The formula has two parts:

  • \(\mathrm{Cu}\): the element copper
  • \(\mathrm{SO_4}\): the polyatomic ion sulfate

Sulfate is treated as a single unit in ionic naming and charge accounting.

Step 2: Determine ion charges and the oxidation state of copper

The sulfate ion has a well-known charge of \(-2\):

\[ \mathrm{SO_4^{2-}} \]

Ionic compounds are neutral overall, so the copper ion must supply a \(+2\) charge to balance sulfate:

\[ (+2) + (-2) = 0 \quad \Rightarrow \quad \mathrm{Cu^{2+}} \]

Therefore, copper has oxidation state \(+2\) in \(\mathrm{CuSO_4}\).

Step 3: Write the correct name

Copper is a transition metal with more than one common ionic charge, so the Stock system uses a Roman numeral to show the charge:

  • \(\mathrm{Cu^{2+}}\) is copper(II)
  • \(\mathrm{SO_4^{2-}}\) is sulfate

The name is copper(II) sulfate.

Ionic composition and naming of CuSO4 A readable diagram showing a copper two plus ion, a sulfate two minus ion with sulfur and four oxygens, and the neutral product CuSO4 in a one to one ratio. CuSO₄: ions, charges, and 1:1 charge balance Copper(II) sulfate is formed from Cu²⁺ and SO₄²⁻, so one cation balances one sulfate anion. Copper ion Cu 2+ cation oxidation state of copper = +2 Sulfate ion S O O O O 2− 1 S atom + 4 O atoms, overall charge −2 combine forms Neutral salt CuSO₄ copper(II) sulfate 1 Cu²⁺ : 1 SO₄²⁻ (+2) + (−2) = 0 CuSO₄ is copper(II) sulfate because Cu must be +2 to balance sulfate, SO₄²⁻.
\(\mathrm{CuSO_4}\) forms by combining \(\mathrm{Cu^{2+}}\) with \(\mathrm{SO_4^{2-}}\) in a \(1:1\) ratio to achieve overall charge neutrality.

Step 4: Write the dissociation equation (common aqueous chemistry use)

In water, copper(II) sulfate dissociates into ions:

\[ \mathrm{CuSO_4(s) \rightarrow Cu^{2+}(aq) + SO_4^{2-}(aq)} \]

Step 5: Compute the molar mass of \(\mathrm{CuSO_4}\)

Add the atomic masses of one copper, one sulfur, and four oxygens. Using typical periodic table values \(M(\mathrm{Cu}) = 63.55\ \text{g/mol}\), \(M(\mathrm{S}) = 32.07\ \text{g/mol}\), \(M(\mathrm{O}) = 16.00\ \text{g/mol}\):

\[ M(\mathrm{CuSO_4}) = 63.55 + 32.07 + 4 \cdot 16.00 = 63.55 + 32.07 + 64.00 = 159.62\ \text{g/mol} \]

Component Count Atomic mass (g/mol) Contribution (g/mol)
Copper (Cu) \(1\) \(63.55\) \(1 \cdot 63.55 = 63.55\)
Sulfur (S) \(1\) \(32.07\) \(1 \cdot 32.07 = 32.07\)
Oxygen (O) \(4\) \(16.00\) \(4 \cdot 16.00 = 64.00\)
Total \(159.62\ \text{g/mol}\)

Common clarification: hydrates vs anhydrous \(\mathrm{CuSO_4}\)

The formula \(\mathrm{CuSO_4}\) refers to the anhydrous salt. A frequently encountered hydrated form is copper(II) sulfate pentahydrate, \(\mathrm{CuSO_4\cdot 5H_2O}\), which has additional mass from water molecules and is named separately.

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