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General Chemistry • Chemical Compounds
Name the cation first and the anion second, using the standard polyatomic ion name (such as sulfate or nitrate). If the metal can have multiple charges, include a Roman numeral to show its oxidation state.
Parentheses are used when a polyatomic ion repeats more than once in the formula. The subscript outside the parentheses multiplies every atom inside the polyatomic ion.
It uses charge balance: the total positive charge from the cation(s) must equal the total negative charge from the anion(s). The metal oxidation state is the charge that makes the overall compound neutral.
Ammonium is the polyatomic cation NH4+ and is named "ammonium" in the compound name. For example, (NH4)2CO3 is ammonium carbonate.
No, it is designed for ionic salts that contain ions, including polyatomic ions. Binary molecular compounds of nonmetals use Greek-prefix naming rules instead.