Theory — Gas Thermometer Scale Builder
A gas thermometer is one of the most conceptually direct ways to define temperature:
in the ideal-gas limit, the pressure at constant volume (or the volume at constant pressure) is proportional to absolute temperature.
Using measured data, we can build a temperature scale and extrapolate to estimate absolute zero.
1) Ideal-gas proportionality
From the ideal gas law \(PV=nRT\):
In real gases, the best approximation occurs at low pressure (closer to ideal behavior).
2) Linear model and calibration
The calculator fits a line using Kelvin temperature:
Two common calibration approaches:
- Two-point calibration (e.g., ice point \(0^\circ\text{C}\) and steam point \(100^\circ\text{C}\))
- Direct calibration where each data row includes a measured \(T\) and \(X\)
3) Extrapolating to absolute zero
If the line is \(X=aT_K+b\), then setting \(X=0\) gives:
If you force the fit through the origin (\(b=0\)), you are imposing the ideal-gas constraint \(X\propto T_K\),
so \(X=0\) corresponds exactly to \(T_K=0\) by construction (no estimated intercept).
4) What the plot shows
- Data points: measured \\((T_K, X)\\)
- Best-fit line (revealed progressively by \\(\tau\\))
- Extrapolated intercept at \\(X=0\\) (estimated absolute zero, when applicable)