Molecular Speed Calculator — Theory
In kinetic theory, gas molecules have a range of speeds. For an ideal gas in thermal equilibrium,
the speed distribution is Maxwell–Boltzmann (non-relativistic). Three standard “summary” speeds are:
most probable \(v_{mp}\), mean speed \(\langle v\rangle\), and root-mean-square speed \(v_{rms}\).
1) Characteristic speeds
2) Using molar mass \(M\): the \(RT/M\) forms
If you use molar mass \(M\) (kg/mol), relate it to molecular mass via \(m=M/N_A\) and \(R=N_Ak\).
Then:
3) Ordering and ratios (shape constants)
The three speeds satisfy \(v_{mp}<\langle v\rangle < v_{rms}\). Their ratios do not depend on the gas:
4) Maxwell–Boltzmann speed distribution
The probability density for the speed magnitude \(v\ge 0\) is:
5) University note: 3D components
Each Cartesian velocity component (e.g., \(v_x\)) follows a 1D Gaussian with rms:
6) Relativistic tease (when MB fails)
Maxwell–Boltzmann is non-relativistic. If typical speeds become a significant fraction of \(c\),
you need a relativistic distribution (Maxwell–Jüttner) and relativistic kinetic energy.
For ordinary gases near room temperature, \(v/c\) is extremely small.
Sample (air at 300 K)
With \(M\approx 29\ \text{g/mol}\) and \(T=300\ \text{K}\), typical results are
\(v_{rms}\sim 5\times 10^2\ \text{m/s}\),
\(\langle v\rangle\sim 4.6\times10^2\ \text{m/s}\),
\(v_{mp}\sim 4.1\times10^2\ \text{m/s}\).
Small differences arise from the exact molar mass used.