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General Chemistry • Matter Its Properties and Measurement
Leading zeros are not significant, but nonzero digits are significant and trailing zeros after a decimal point are significant. In 0.004560 the significant digits are 4, 5, 6, and 0, so it has 4 significant figures.
Without a decimal point, trailing zeros in integers can be ambiguous because they may be placeholders rather than measured precision. The calculator lets you choose the convention by toggling whether those trailing zeros are treated as significant.
For multiplication or division, the result is rounded to the same number of significant figures as the input with the fewest significant figures. This preserves the measured precision of the least-precise factor.
For addition or subtraction, the result is rounded to the least number of decimal places among the inputs. This is why the add/subtract mode expects plain decimals rather than scientific notation.
Scientific notation makes the intended precision explicit because all digits in the mantissa are significant. For example, 1.230e3 has 4 significant figures because the mantissa 1.230 has four digits of precision.