Lewis diagrams for atoms and simple ions
A Lewis diagram (Lewis dot symbol) represents an atom or ion using:
- the element symbol for the nucleus and inner electrons, and
- dots around the symbol for the valence electrons only (up to 8).
The dots are arranged on four “sides” of the symbol (top, right, bottom, left),
with a maximum of two electrons per side (one pair).
1. Valence electrons of neutral atoms
For main-group elements, the number of valence electrons is given by the
group number (using the 1–2 and 13–18 convention). In a simple rule:
For example, oxygen is in group 16, so
\(
N_{\text{valence}}(\mathrm{O}) = 16 - 10 = 6
\).
Neon is in group 18, so
\(
N_{\text{valence}}(\mathrm{Ne}) = 8
\).
Hydrogen and helium are special cases: H has 1 valence electron;
He has 2 valence electrons (a filled first shell).
2. Adjusting valence electrons for simple ions
When an atom forms a simple ion, electrons are lost (cations) or gained (anions).
If \(q\) is the ionic charge (in units of \(\text{e}\)), then:
-
For a cation (\(q > 0\)), valence electrons are removed
(fewer dots in the Lewis diagram).
-
For an anion (\(q < 0\)), valence electrons are added
(more dots, up to an octet).
In practice, Lewis diagrams are usually drawn only for species with
\(0 \le N_{\text{valence}} \le 8\).
3. Placing the electrons around the symbol
To draw the Lewis diagram for an atom or simple ion:
- Determine \(N_{\text{valence, neutral}}\) from the group number.
- Adjust for the charge using
\(N_{\text{valence}}(\text{ion}) =
N_{\text{valence, neutral}} - q\).
- Write the element symbol (with charge as a superscript for ions).
-
Place dots one by one around the symbol:
- First, put one electron per side (top, right, bottom, left).
- Then start pairing electrons on each side until you reach the
total number of valence electrons.
Examples:
-
\(\mathrm{Cl}\): 7 valence electrons → seven dots around the symbol
(three pairs and one unpaired electron).
-
\(\mathrm{Cl^-}\): 8 valence electrons → four pairs around the symbol
(octet, often drawn in brackets with a superscript “−”).
-
\(\mathrm{Na}\): 1 valence electron (one dot);
\(\mathrm{Na^+}\): 0 valence electrons (no dots; symbol with “+” charge).
The calculator on this page follows these rules to count valence electrons
for a chosen atom or simple ion and to place the dots in the correct order
(one per side before pairing).