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Nitrogen Electron Configuration (N)

What is the nitrogen electron configuration (ground state), and how is it obtained from nitrogen’s atomic number using the aufbau principle, Pauli exclusion principle, and Hund’s rule?

Subject: General Chemistry Chapter: Electrons in Atoms Topic: Electron Configuration Answer included
nitrogen electron configuration electron configuration of nitrogen N electron configuration nitrogen orbital diagram 1s2 2s2 2p3 [He] 2s2 2p3 aufbau principle Hund's rule
Accepted answer Answer included

Nitrogen electron configuration (ground state)

The nitrogen electron configuration describes how the electrons of a neutral nitrogen atom are distributed among orbitals in the lowest-energy (ground) state. Nitrogen has atomic number \(Z=7\), meaning 7 protons and (for a neutral atom) 7 electrons.

Final result: 1s2 2s2 2p3 (noble-gas shorthand: [He] 2s2 2p3).

Step 1: Use atomic number to get total electrons

For a neutral atom, the electron count equals the atomic number: \[ n_e = Z = 7 \]

Step 2: Fill orbitals in aufbau order

The aufbau principle fills lower-energy orbitals first. For the first two shells relevant to nitrogen, the order is: 1s → 2s → 2p.

Subshell Max electrons Electrons placed (nitrogen) Running total
1s 2 2 2
2s 2 2 4
2p 6 3 7

After filling 1s and 2s, \(7 - 4 = 3\) electrons remain, so they go into the 2p subshell: 2p3.

Step 3: Apply Pauli exclusion and Hund’s rule (orbital diagram meaning)

  • Pauli exclusion principle: an orbital holds at most 2 electrons, and if 2 are present they must have opposite spins.
  • Hund’s rule: in a set of equal-energy orbitals (the three 2p orbitals), electrons occupy them singly with parallel spins before pairing.

Visualization: nitrogen orbital diagram for 1s2 2s2 2p3

Nitrogen (Z = 7): orbital diagram for 1s² 2s² 2p³ higher Energy lower 2p 2s 1s Legend 1. Lower energy subshells fill first (Aufbau). 2. Each box holds max 2 electrons (Pauli). 3. Unpaired electrons share same spin in 2p (Hund). 4. Arrows (↿⇂) indicate electron spin direction. Neutral Nitrogen has 7 electrons: 1s² 2s² 2p³. The three 2p electrons are unpaired.
In nitrogen, the 2p subshell is half-filled with three electrons in separate orbitals, all with parallel spins (Hund's rule).

Useful interpretations for general chemistry

Nitrogen is in period 2 and group 15. Its valence-shell configuration is 2s2 2p3, so it has 5 valence electrons and commonly forms three covalent bonds (with one lone pair) in many neutral molecules.

Answer

The nitrogen electron configuration for a neutral nitrogen atom is 1s2 2s2 2p3 (or [He] 2s2 2p3), and the orbital diagram shows paired electrons in 1s and 2s plus three unpaired electrons distributed one per 2p orbital.

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