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HNO2 Acid Name (Naming the Oxoacid)

What is the acid name of HNO2, and how is it determined from the corresponding oxyanion?

Subject: General Chemistry Chapter: Chemical Compounds Topic: Naming Oxoacids Answer included
hno2 acid name HNO2 name nitrous acid nitrite ion NO2- oxoacid naming oxyacid nomenclature nitric acid vs nitrous acid
Accepted answer Answer included

HNO2 Acid Name

The keyword “hno2 acid name” asks for the correct nomenclature of the oxoacid \( \mathrm{HNO_2} \). Oxoacids are named by identifying the corresponding oxyanion and then applying a consistent suffix change.

Direct name: \( \mathrm{HNO_2} \) is nitrous acid.

The name comes from the nitrite ion \( \mathrm{NO_2^-} \) using the rule “-ite” \(\rightarrow\) “-ous acid.”

Step-by-step naming from the oxyanion

For an oxoacid \( \mathrm{H_{x}AO_{y}} \), remove \( \mathrm{H^+} \) conceptually to find the oxyanion \( \mathrm{A O_y^{\,n-}} \), then translate the anion name into the acid name.

  1. Identify the oxyanion. Removing one \( \mathrm{H^+} \) from \( \mathrm{HNO_2} \) gives the conjugate base:

    \[ \mathrm{HNO_2 \;\rightleftharpoons\; H^+ + NO_2^-} \]

    The anion \( \mathrm{NO_2^-} \) is called nitrite.

  2. Apply the oxoacid suffix rule.

    • -ite (anion) \(\rightarrow\) -ous acid (acid)
    • -ate (anion) \(\rightarrow\) -ic acid (acid)

    Since the anion is nitrite, the acid is nitrous acid.

Quick comparison table (avoids the most common mix-up)

Oxyanion Oxyanion name Corresponding acid Acid name Suffix pattern
\( \mathrm{NO_2^-} \) nitrite \( \mathrm{HNO_2} \) nitrous acid -ite \(\rightarrow\) -ous
\( \mathrm{NO_3^-} \) nitrate \( \mathrm{HNO_3} \) nitric acid -ate \(\rightarrow\) -ic

Common error: Calling \( \mathrm{HNO_2} \) “nitric acid.” Nitric acid corresponds to nitrate \( \mathrm{NO_3^-} \), not nitrite \( \mathrm{NO_2^-} \).

Visualization: from anion name to acid name

Oxoacid naming map for nitrite/nitrate A flowchart linking NO2- (nitrite) to HNO2 (nitrous acid) and NO3- (nitrate) to HNO3 (nitric acid), highlighting -ite to -ous and -ate to -ic. \(\mathrm{NO_2^-}\) nitrite \(\mathrm{NO_3^-}\) nitrate “-ite” \(\rightarrow\) “-ous acid” “-ate” \(\rightarrow\) “-ic acid” \(\mathrm{HNO_2}\) nitrous acid \(\mathrm{HNO_3}\) nitric acid
The diagram shows the naming pathway: \( \mathrm{NO_2^-} \) (nitrite) leads to \( \mathrm{HNO_2} \) (nitrous acid) via “-ite” \(\rightarrow\) “-ous,” while \( \mathrm{NO_3^-} \) (nitrate) leads to \( \mathrm{HNO_3} \) (nitric acid) via “-ate” \(\rightarrow\) “-ic.”

Final answer

The acid name of \( \mathrm{HNO_2} \) is nitrous acid, because its conjugate base is the nitrite ion \( \mathrm{NO_2^-} \) and nitrite-type oxoacids take the “-ous acid” ending.

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