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H2 Lewis structure: shared electron pair and the hydrogen duet rule

What is the correct H2 Lewis structure, and how does it satisfy the duet rule for hydrogen?

Subject: General Chemistry Chapter: Chemical Bonds Topic: Lewis Structure of Diatomic Molecules Single Bonds Answer included
h2 lewis structure Lewis structure H2 hydrogen molecule diatomic molecule single covalent bond duet rule valence electrons bonding pair
Accepted answer Answer included

h2 lewis structure is the Lewis (electron-dot) representation of the hydrogen molecule, \(\mathrm{H_2}\). It is written as \(\mathrm{H{-}H}\) (or \(\mathrm{H{:}H}\)), where the line (or colon) denotes one shared electron pair.

Valence electrons and the duet rule

Each hydrogen atom has one valence electron. The molecule therefore contains two valence electrons in total, and a stable arrangement places both electrons between the two nuclei. In Lewis-structure language, each hydrogen “counts” the shared pair and reaches a duet (2 electrons in its 1s valence shell).

Species Valence electrons per atom Number of atoms Total valence electrons
H \(1\) \(2\) \(2\)

Compact Lewis forms

\(\mathrm{H{-}H}\) and \(\mathrm{H{:}H}\) are equivalent notations for one bonding pair (2 electrons) shared between two hydrogens.

Bond order and formal-charge check

\(\mathrm{H_2}\) contains one single bond, so the bond order is 1. Formal charge on each hydrogen is zero in the Lewis structure because each hydrogen is assigned one electron from the shared pair.

\[ \mathrm{FC} = V - \left(N + \frac{B}{2}\right) \]

For each H in \(\mathrm{H{-}H}\): \(V=1\), \(N=0\), \(B=2\), so \(\mathrm{FC} = 1 - (0 + 2/2) = 0\).

Visualization of the H2 Lewis structure

Lewis structure of H2: one shared electron pair between two hydrogen atoms Two hydrogen atoms are connected by a single bond. Two electrons are shown as a paired set of dots between the atoms, indicating the shared bonding pair that gives each hydrogen a duet. H₂ Lewis structure (single bond) One bonding pair (2 e−) shared between two H atoms; each H attains a duet. H H shared pair (2 e−) each H counts 2 electrons each H counts 2 electrons
The Lewis diagram \(\mathrm{H{-}H}\) represents a single covalent bond formed by a shared electron pair; hydrogen follows a duet rule rather than an octet rule.

Meaning and limitations of the Lewis picture

  • Electron-pair bookkeeping: the line indicates two electrons shared between atoms, not a literal rod between nuclei.
  • Three-dimensional shape: all diatomic molecules are linear by definition, so no bond-angle construction is needed.
  • Orbital detail: the Lewis structure does not show 1s–1s overlap or the bonding/antibonding molecular orbitals; it only encodes connectivity and electron pairs.

Summary statement

\(\mathrm{H_2}\) is correctly drawn as \(\mathrm{H{-}H}\), containing two total valence electrons arranged as one bonding pair that satisfies the duet rule for both hydrogen atoms with formal charges of zero.

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