Density of ethyl acetate
Density ethyl acetate values quantify how much mass is contained in a given volume of the liquid. In laboratory settings, density supports routine conversions between measured volume (mL) and required mass (g), and it provides a quick check for purity and temperature effects.
Definition and units
Density is defined as mass per unit volume:
Common units for liquids include g/mL and g/cm3 (numerically identical), and the SI unit kg/m3.
Reference value and temperature dependence
For pure ethyl acetate (C4H8O2), a widely used classroom/lab reference at room temperature is \(\rho \approx 0.90~\text{g/mL}\). A representative value at \(20~^\circ\text{C}\) is often taken as \(\rho \approx 0.902~\text{g/mL}\), corresponding to about \(902~\text{kg/m}^3\).
Density decreases as temperature increases because liquids expand. Small temperature shifts typically produce modest changes, but precision work benefits from using the density reported at the measurement temperature.
| Quantity | Representative value | Meaning for calculations |
|---|---|---|
| Density at ~room temperature | \(\rho \approx 0.90~\text{g/mL}\) | Each 1 mL of liquid corresponds to about 0.90 g of mass. |
| Density at \(20~^\circ\text{C}\) | \(\rho \approx 0.902~\text{g/mL}\) | Useful when glassware and lab references are standardized near 20 °C. |
| SI form (same value) | \(\rho \approx 900~\text{kg/m}^3\) | Convenient for fluid-mechanics style calculations. |
Mass–volume conversions
Rearranging \(\rho = \frac{m}{V}\) yields the two practical conversion forms:
- Mass from a measured volume: \(m = (0.902~\text{g/mL})(V~\text{in mL})\).
- Volume from a measured mass: \(V = \frac{m~\text{in g}}{0.902~\text{g/mL}}\).
- Consistency check: a larger volume at the same temperature implies a proportionally larger mass.
Typical numerical examples
Example A: mass of a given volume
A sample has volume \(V = 125~\text{mL}\) at \(20~^\circ\text{C}\). Using \(\rho = 0.902~\text{g/mL}\),
Example B: volume of a given mass
A measured mass is \(m = 50.0~\text{g}\) at \(20~^\circ\text{C}\). With \(\rho = 0.902~\text{g/mL}\),
Visualization of the mass–volume relationship
The graph shows \(m\) versus \(V\) for ethyl acetate using \(\rho \approx 0.90~\text{g/mL}\). The straight line through the origin expresses \(m=\rho V\), and the slope equals the density.
Common pitfalls and checks
- Temperature mismatch: density values at \(20~^\circ\text{C}\) and \(25~^\circ\text{C}\) differ; higher temperature implies lower density.
- Unit inconsistency: mixing mL with L or g with kg without conversion shifts results by factors of \(10^3\).
- Significant figures: the reported density and the measured volume/mass jointly control the final rounding.
- Purity effects: dissolved impurities and residual water can shift the observed density away from a reference value.