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Atoms to Moles Conversion Using Avogadro’s Number

Using Avogadro’s number \(N_A = 6.022 \times 10^{23}\ \mathrm{mol^{-1}}\), how many moles correspond to \(1.50 \times 10^{24}\) atoms of Al, and how many atoms are in \(0.250\ \mathrm{mol}\) of Al?

Subject: General Chemistry Chapter: Chemical Compounds Topic: Mole and Avogadros Number Answer included
atoms to moles Avogadro's number Avogadro constant mole conversion number of atoms moles to atoms amount of substance scientific notation
Accepted answer Answer included

Key idea for atoms to moles

The conversion from atoms to moles uses Avogadro’s number (Avogadro’s constant), \(N_A = 6.022 \times 10^{23}\ \mathrm{mol^{-1}}\), which means \(6.022 \times 10^{23}\) atoms correspond to \(1\ \mathrm{mol}\) of atoms.

Two inverse relationships control the entire topic:

\[ n = \frac{N}{N_A} \qquad\text{and}\qquad N = n \times N_A \]

where \(N\) is the number of atoms (a count) and \(n\) is the amount in moles.

Worked example 1: \(1.50 \times 10^{24}\) atoms of Al to moles

  1. Identify given and desired quantities.
    Given \(N = 1.50 \times 10^{24}\) atoms Al and \(N_A = 6.022 \times 10^{23}\ \mathrm{mol^{-1}}\). Desired \(n\) in moles.
  2. Use the atoms to moles formula. \[ n = \frac{N}{N_A} = \frac{1.50 \times 10^{24}}{6.022 \times 10^{23}}\ \mathrm{mol} \]
  3. Compute the power-of-ten part and the decimal part. \[ \frac{10^{24}}{10^{23}} = 10^{1} \] \[ n = \left(\frac{1.50}{6.022}\right) \times 10^{1}\ \mathrm{mol} = 0.249 \times 10^{1}\ \mathrm{mol} = 2.49\ \mathrm{mol} \]
  4. Significant figures. \(1.50 \times 10^{24}\) has 3 significant figures, so the result is reported as \(2.49\ \mathrm{mol}\).

Worked example 2: \(0.250\ \mathrm{mol}\) of Al to atoms

  1. Identify given and desired quantities.
    Given \(n = 0.250\ \mathrm{mol}\). Desired \(N\) in atoms.
  2. Use the moles to atoms formula. \[ N = n \times N_A = 0.250 \times (6.022 \times 10^{23}) \]
  3. Multiply and report in scientific notation. \[ N = (0.250 \times 6.022)\times 10^{23} = 1.5055 \times 10^{23} \approx 1.51 \times 10^{23}\ \text{atoms} \]

Summary table

Conversion goal Relationship Example input Example result
Atoms to moles \(n = \dfrac{N}{N_A}\) \(N = 1.50 \times 10^{24}\) atoms Al \(n = 2.49\ \mathrm{mol}\)
Moles to atoms \(N = n \times N_A\) \(n = 0.250\ \mathrm{mol}\) Al \(N = 1.51 \times 10^{23}\) atoms

Visualization: the two-way “count ⇄ amount” map

Atoms (count) \(N\) atoms Example: \(1.50 \times 10^{24}\) Avogadro’s number \(N_A = 6.022 \times 10^{23}\ \mathrm{mol^{-1}}\) divide by \(N_A\) result \(n\) Moles (amount) \(n\ \mathrm{mol}\) “1 mol” sample Example: \(2.49\ \mathrm{mol}\) multiply by \(N_A\) to return to atoms Unit check: \(\dfrac{\text{atoms}}{\mathrm{mol^{-1}}}=\mathrm{mol}\) and \(\mathrm{mol}\times \mathrm{mol^{-1}}=\text{atoms}\)
The atoms to moles conversion divides a particle count by \(N_A\); the reverse conversion multiplies moles by \(N_A\).

Final answers

\(1.50 \times 10^{24}\) atoms of Al correspond to \(2.49\ \mathrm{mol}\) of Al, and \(0.250\ \mathrm{mol}\) of Al contains \(1.51 \times 10^{23}\) atoms.

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